Phase behavior of short-range square-well model.

نویسندگان

  • D L Pagan
  • J D Gunton
چکیده

Various Monte Carlo techniques are used to determine the complete phase diagrams of the square-well model for the attractive ranges lambda = 1.15 and lambda = 1.25. The results for the latter case are in agreement with earlier Monte Carlo simulations for the fluid-fluid coexistence curve and yield new results for the liquidus-solidus lines. Our results for lambda = 1.15 are new. We find that the fluid-fluid critical point is metastable for both cases, with the case lambda = 1.25 being just below the threshold value for metastability. We compare our results with prior studies and with experimental results for the gamma(II)-crystallin.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

The influence of short-range attractive and repulsive interactions on the phase behaviour of model colloidal suspensions

The phase behaviour of simple systems interacting via model pair potentials that include both a hard core and additional short-range interactions is predicted using a classical density-functional-perturbation theory. The combination of a narrow attractive square well and a repulsive square barrier, approximating interactions in charge-stabilized colloidal suspensions, gives rise to isostructura...

متن کامل

Modeling the phase behavior of polydisperse rigid rods with attractive interactions with applications to single-walled carbon nanotubes in superacids.

The phase behavior of rodlike molecules with polydisperse length and solvent-mediated attraction and repulsion is described by an extension of the Onsager theory for rigid rods. A phenomenological square-well potential is used to model these long-range interactions, and the model is used to compute phase separation and length fractionation as a function of well depth and rod concentration. The ...

متن کامل

Phase Behavior of the Restricted Primitive Model and Square-Well Fluids from Monte Carlo Simulations in the Grand Canonical Ensemble

Coexistence curves of square-well fluids with variable interaction width and of the restricted primitive model for ionic solutions have been investigated by means of grand canonical Monte Carlo simulations aided by histogram reweighting and multicanonical sampling techniques. It is demonstrated that this approach results in efficient data collection. The shape of the coexistence curve of the sq...

متن کامل

Comparison of the hyperbolic range of two-fluid models on two-phase gas -liquid flows

In this paper, a numerical study is conducted in order to compare hyperbolic range of equations of isotherm two-fluid model governing on two-phase flow inside of pipe using conservative Shock capturing method. Differential equations of the two-fluid model are presented in two forms (i.e. form I and form II). In forms I and II, pressure correction terms are hydrodynamic and hydrostatic, respecti...

متن کامل

Modified Spin Wave Thoery of the Bilayer Square Lattice Frustrated Quantum Heisenberg Antiferromagnet

The ground state of the square lattice bilayer quantum antiferromagnet with nearest and next-nearest neighbour intralayer interaction is studied by means of the modified spin wave method. For weak interlayer coupling, the ground state is found to be always magnetically ordered while the quantum disordered phase appear for large enough interlayer coupling. The properties of the disordered phase ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 122 18  شماره 

صفحات  -

تاریخ انتشار 2005